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Process for the preparation of transition metals a

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专利名称:Process for the preparation of transition

metals as well as their oxides

发明人:HERRMANN, WOLFGANG A., PROF. DR. DR.

H.C.,FISCHER, RICHARD W., DIPL.-CHEM.

申请号:EP93112262.6申请日:19930730公开号:EP0636575A1公开日:19950201

摘要:There is described a process for preparing transition metals of the groups VIIBand VIIIB of the Periodic Table with the exception of Fe, Co and Ni in metallic form or asoxide, by decomposition of corresponding volatile transition metal compounds, whereinthe transition metal compounds used are organometallic oxides of the general formulaRaMebOc (I), where R is -a saturated or unsaturated, substituted or unsubstituted alkylradical having from 1 to 12 carbon atoms, -a monocyclic or polycyclic hydrocarbon havingfrom 3 to 12 carbon atoms -a substituted or unsubstituted aryl group having from 6 to10 carbon atoms or -an aromatic pi -bonded ligand having from 5 to 8 carbon atoms inthe ring, Me = the transition metal concerned, O = oxygen and a has a value from 1 to 12,b has a value from 1 to 3, c has a value from 1 to 8.o

申请人:SKW TROSTBERG AKTIENGESELLSCHAFT

地址:Dr.-Albert-Frank-Strasse 32 D-83308 Trostberg DE

国籍:DE

代理机构:Huber, Bernhard, Dipl.-Chem.

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